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Multimedia distribution and health risk assessment of typical organic pollutants in a retired industrial

《环境科学与工程前沿（英文）》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1742-9

摘要：

● A fine portrayal of organic pollutants in a retired industrial park is provided.

关键词： Organic pollutants     Retired industrial park     Spatial correlation     Health risk assessment    

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Immobilization of laccase on organic–inorganic nanocomposites and its application in the removal of phenolicpollutants

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 867-879 doi: 10.1007/s11705-022-2277-5

摘要： Polydopamine-functionalized nanosilica was synthesized using an inexpensive and easily obtainable raw material, mild reaction conditions, and simple operation. Subsequently, a flexible spacer arm was introduced by using dialdehyde starch as a cross-linking agent to bind with laccase. A high loading amount (77.8 mg∙g‒1) and activity retention (75.5%) could be achieved under the optimum immobilization conditions. Thermodynamic parameters showed that the immobilized laccase had a lower thermal deactivation rate constant and longer half-life. The enhancement of thermodynamic parameters indicated that the immobilized laccase had better thermal stability than free laccase. The residual activity of immobilized laccase remained at about 50.0% after 30 days, which was 4.0 times that of free laccase. Immobilized laccase demonstrated excellent removal of phenolic pollutants (2,4-dichlorophenol, bisphenol A, phenol, and 4-chlorophenol) and perfect reusability with 70% removal efficiency retention for 2,4-dichlorophenol after seven cycles. These results suggested that immobilized laccase possessed great reusability, improved thermal stability, and excellent storage stability. Organic–inorganic nanomaterials have a good application prospect for laccase immobilization, and the immobilized laccase of this work may provide a practical application for the removal of phenolic pollutants.

关键词： polydopamine     pollutant removal     thermodynamic     phenolic pollutants     immobilized laccase    

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Addressing the environmental risk of persistent organic pollutants in China

Bin WANG, Jun HUANG, Shubo DENG, Xiaoling YANG, Gang YU

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 2-16 doi: 10.1007/s11783-011-0370-y

摘要： The Stockholm Convention on persistent organic pollutants (POPs) was adopted in 2001. This year is the 10th anniversary of the adoption of the Convention. Until now, 22 chemicals or chemical categories have been listed as POPs in the Stockholm Convention. The POPs Research Center was established in Tsinghua University in the same year when the Convention was adopted. In the last ten years, much work has been done by Chinese researchers to understand the environmental risk of POPs in China. This article aims to review the recent research progress of our POPs Research Center and some other Chinese researchers’ studies in addressing the environmental risk of POPs, including the priority screening and inventory study of POPs, monitoring and modeling of POPs pollution and exposure, and environmental risk assessment and modeling of POPs. Although great advances in addressing the environmental risk of POPs have been made in recent years, we are still facing quite a few problems, such as data scarcity and uncertainty in environmental risk assessment of POPs. The study on the effect of POPs mixtures is in its infancy and currently POPs are usually assessed from legal perspective by risk assessment of single chemicals. These problems should be well addressed by further efforts. Further studies should also be taken in future to study environment risk of POPs by considering aspects of coupled dynamics between climate processes and POPs. Such sound scientific, risk-based information can support decision-making aiming to effectively minimize the risk level of POPs.

关键词： persistent organic pollutant (POPs)     environmental risk assessment     inventory     environmental monitoring     fugacity model     emerging POPs    

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DEGRADATION OF ORGANIC POLLUTANTS IN FLOCCULATED LIQUID DIGESTATE USING PHOTOCATALYTIC TITANATE NANOFIBERS

《农业科学与工程前沿（英文）》 2023年 第10卷 第3期   页码 492-502 doi: 10.15302/J-FASE-2023503

摘要：

● Titanate NFs were synthesized and photodegraded liquid digestate for the first time.

关键词： titanate nanofibers     photocatalysis     poultry litter liquid digestate    

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Corrigendum to “Emerging Organic Contaminants in Chinese Surface Water: Identification of Priority Pollutants Corrigendum

Mengmeng Zhong, Tielong Wang, Wenxing Zhao, Jun Huang, Bin Wang, Lee Blaney, Qingwei Bu, Gang Yu

《工程（英文）》 2023年 第31卷 第12期   页码 139-140 doi: 10.1016/j.eng.2022.09.001

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Endosulfan in the Chinese environment: monitoring and modeling

Hongliang JIA, Liyan LIU, Yeqing SUN, Daoji CAI, Jianxin HU, Nanqi REN, Yifan LI

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 32-44 doi: 10.1007/s11783-011-0375-6

摘要： This paper reviews the usage and emissions of endosulfan, the newest member of the persistent organic pollutants (POPs), in China, and its fate and behavior in Chinese environment. Endosulfan usage in China has been estimated to be approximately 25700 t between 1994 and 2004. Concentrations of endosulfan in different environmental compartments in China, such as air, soil, water, and biota, but focusing at air and surface soil, have been summarized. Concentrations of total endosulfan in surface soil across China were ranged from below detection limit (BDL) to 19000 pg·g dry weight (dw), with geometric mean of 120 pg·g dw. The results indicated that endosulfan sulfate had highest concentration in Chinese soil, followed by - and -endosulfan. Air concentrations of endosulfan in China were ranged 0–340 pg·m for -endosulfan and 0–121 pg·m for -endosulfan, with high concentrations occurred in the cotton production areas. Gridded usage inventories of endosulfan on a fine gridded system with a 1/4° longitude by 1/6° latitude resolution were compiled, from which, emission to air and residues in soil of endosulfan were calculated in each grid by using a modified simplified gridded pesticide emission and residue model (SGPERM), an integrated modeling system combining mathematical model, database management system, and geographic information system. Total emissions were around 10800 t from 1994 to 2004. Based on the emission and residue inventories, concentrations of - and -endosulfan in Chinese air and agricultural surface soil were also calculated for each grid cell, which are in general consistent with the published monitoring data.

关键词： endosulfan     monitoring     modeling     inventories     persistent organic pollutants     persistent organic pollutants (POPs)    

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Perfluoroalkane acids in human milk under the global monitoring plan of the Stockholm Convention on Persistent OrganicPollutants (2008–2019)

《环境科学与工程前沿（英文）》 2022年 第16卷 第10期 doi: 10.1007/s11783-022-1541-8

摘要：

● Perfluorooctanesulfonic acid and perfluorooctanoic acid highest in human milk.

关键词： Human biomonitoring     Human breast milk     LC-MS/MS analysis     Lifestyle parameters    

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Predictive models on photolysis and photoinduced toxicity of persistent organic chemicals

Qing ZHANG

《环境科学与工程前沿（英文）》 2013年 第7卷 第6期   页码 803-814 doi: 10.1007/s11783-013-0547-7

摘要： Photodegradation is a major abiotic transformation pathway of toxic chemicals in the environment, which in some cases might lead to photoinduced toxicities. The data on photodegradation kinetics and photoinduced toxicities of organic chemicals are essential for their risk assessment. However, the relevant data are only available for a limited number of chemicals, due to the difficulty and high cost of experimental determination. Quantitative structure-activity relationship (QSAR) models that relate photodegradation kinetics or photoinduced toxicity of organic chemicals with their physicochemical properties or molecular structural descriptors may enable simple and fast estimation of their photochemical behaviors. This paper reviews the QSAR models on photodegradation quantum yields and rate constants for toxic organic chemicals in different media including liquid phase, gaseous phase, surfaces of plant leaves, and QSAR models on photoinduced toxicity of organic chemicals to plants, bacteria, and aquatic invertebrates. Further prospects for QSAR model development on photodegradation kinetics and photoinduced toxicity of refractory organic chemicals are proposed.

关键词： quantitative structure-activity relationship (QSAR) models     photodegradation     persistent organic pollutants     environmental media     mechanisms    

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Kinetics of enhanced adsorption by polarization for organic pollutants on activated carbon fiber

HAN Yanhe, QUAN Xie, ZHAO Huimin, CHEN Shuo, ZHAO Yazhi

《环境科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 83-88 doi: 10.1007/s11783-007-0016-2

摘要： The adsorption kinetics for model pollutants on activated carbon fiber (ACF) by polarization was investigated in this work. Kinetics data obtained for the adsorption of these model pollutants at open-circuit, 400 mV, and -400 mV polarization were applied to the Lagergren equation, and adsorption rate constants () were determined. With the anodic polarization of 400 mV, the capacity of sodium phenoxide was increased from 0.0083 mmol/g at open-circuit to 0.18 mmol/g, and a 17-fold enhancement was achieved; however, the capacity of -nitrophenol was decreased from 2.93 mmol/g at open-circuit to 2.65 mmol/g. With the cathodal polarization of -400 mV, the capacity of aniline was improved from 3.60 mmol/g at open-circuit to 3.88 mmol/g; however, the capacity of sodium dodecylbenzene sulfonate was reduced from 2.20 mmol/g at open-circuit to 1.59 mmol/g. The enhancement for electrosorption changed with dif ferent groups substituting. Anodic polarization enhances the adsorption of benzene with the electron-donating group. But whether anodic or not, cathodal polarization had less effect on the adsorption of electron-accepting aromatic compounds, and decreased the adsorption capacity of benzene-bearing donor-conjugate bridge-acceptor, while increasing its adsorption rate. Electrostatic interaction played a very important role in the electrosorption of ion-pollutants.

关键词： ACF     activated     17-fold enhancement     donor-conjugate bridge-acceptor     Electrostatic interaction    

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Effects of a diesel oxidation catalyst on gaseous pollutants and fine particles from an engine operating

Xiaoyan SHI, Kebin HE, Weiwei SONG, Xingtong WANG, Jihua TAN

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 463-469 doi: 10.1007/s11783-011-0317-3

摘要： The effects of a diesel oxidation catalytic (DOC) converter on diesel engine emissions were investigated on a diesel bench at various loads for two steady-state speeds using diesel fuel and B20. The DOC was very effective in hydrocarbon (HC) and CO oxidation. Approximately 90%–95% reduction in CO and 36%–70% reduction in HC were realized using the DOC. Special attention was focused on the effects of the DOC on elemental carbon (EC) and organic carbon (OC) fractions in fine particles (PM ) emitted from the diesel engine. The carbonaceous compositions of PM were analyzed by the method of thermal/optical reflectance (TOR). The results showed that total carbon (TC), OC and EC emissions for PM from diesel fuel were generally reduced by the DOC. For diesel fuel, TC emissions decreased 22%–32% after the DOC depending on operating modes. The decrease in TC was attributed to 35%–97% decrease in OC and 3%–65% decrease in EC emissions. At low load, a significant increase in the OC/EC ratio of PM was observed after the DOC. The effect of the DOC on the carbonaceous compositions in PM from B20 showed different trends compared to diesel fuel. At low load, a slight increase in EC emissions and a significant decrease in OC/EC ratio of PM after DOC were observed for B20.

关键词： diesel oxidation catalyst (DOC)     diesel particulate matters     elemental carbon (EC)     organic carbon (OC)     biodiesel    

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Determination of persistent organic pollutants by gas chromatography/laser multiphoton ionization/time-of-flight

Osamu SHITAMICHI, Taiki MATSUI, Yamei HUI, Weiwei CHEN, Totaro IMASAKA

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 26-31 doi: 10.1007/s11783-011-0374-7

摘要： An authentic mixture of polychlorinated biphenyls was measured using a short wide-bore capillary column for the group separation of major components present in an actual sample of Kanechlor. The limits of detection were improved by ca. 2 fold in comparison with those obtained using a conventional capillary column, since the retention time was reduced and the amount of analytes introduced into the mass spectrometer per unit time could be increased. On the other hand, surface-water and sediment samples containing polycyclic aromatic hydrocarbons (PAHs) were collected from the river located in the vicinity of a waste water treatment plant. Even acenaphthylene, a minor component of the mixture could be measured for the sediment sample, and the concentrations were determined for several heavy PAHs. As demonstrated, a technique involving laser multiphoton ionization/time-of-flight mass spectrometry was useful as a sensitive and selective analytical tool for the trace analysis of persistent organic pollutants in an environmental sample.

关键词： polychlorinated biphenyls (PCBs)     polycyclic aromatic hydrocarbons (PAHs)     laser multiphoton ionization/time-of-flight mass spectrometry (MPI/TOF-MS)    

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Twenty years of achievements in China’s implementation of the Stockholm Convention

《环境科学与工程前沿（英文）》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1587-7

摘要：

● China’s implementation of the SC was systematically studied.

关键词： Stockholm Convention     Persistent organic pollutants     Compliance     Effectiveness    

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The abatement of major pollutants in air and water by environmental catalysis

Junhua LI, Hong HE, Chun HU, Jincai ZHAO

《环境科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 302-325 doi: 10.1007/s11783-013-0511-6

摘要： This review reports the research progress in the abatement of major pollutants in air and water by environmental catalysis. For air pollution control, the selective catalytic reduction of NO (SCR) by ammonia and hydrocarbons on metal oxide and zeolite catalysts are reviewed and discussed, as is the removal of Hg from flue gas by catalysis. The oxidation of Volatile organic compounds (VOCs) by photo- and thermal- catalysis for indoor air quality improvement is reviewed. For wastewater treatment, the catalytic elimination of inorganic and organic pollutants in wastewater is presented. In addition, the mechanism for the procedure of abatement of air and water pollutants by catalysis is discussed in this review. Finally, a research orientation on environment catalysis for the treatment of air pollutants and wastewater is proposed.

关键词： air pollution control     wastewater treatment     DeNOx     selective catalytic reduction (SCR)     Volatile organic compounds (VOCs)     environmental catalysis    

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Efficient elimination of environmental pollutants through sorption-reduction and photocatalytic degradation

Njud S. Alharbi, Baowei Hu, Tasawar Hayat, Samar Omar Rabah, Ahmed Alsaedi, Li Zhuang, Xiangke Wang

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 1124-1135 doi: 10.1007/s11705-020-1923-z

摘要： With the rapid development of industrial, large amounts of different inorganic and organic pollutants are released into the natural environments. The efficient elimination of environmental pollutants, i.e., photocatalytic degradation of persistent organic pollutants into nontoxic organic/inorganic chemicals, solidification or sorption-reduction of heavy metal ions, is crucial to protect the environment. Nanomaterials with large surface area, active sites and abundant functional groups could form strong surface complexes with different kinds of pollutants and thereby could efficiently eliminate the pollutants from the aqueous solutions. In this review, we mainly focused on the recent works about the synthesis of nanomaterials and their applications in the efficient elimination of different organic and inorganic pollutants from wastewater and discussed the interaction mechanism from batch experimental results, the advanced spectroscopy techniques and theoretical calculations. The adsorption and the photocatalytic reduction of organic pollutants and the sorption/reduction of heavy metal ions are generally considered as the main methods to decrease the concentration of pollutants in the natural environment. This review highlights a new way for the real applications of novel nanomaterials in environmental pollution management, especially for the undergraduate students to understand the recent works in the elimination of different kinds of inorganic and organic chemicals in the natural environmental pollution management.

关键词： nanomaterials     sorption-reduction     photocatalytic degradation     organic pollutants     heavy metal ions    

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Fabrication of highly efficient Bi

Wei Mao, Lixun Zhang, Tianye Wang, Yichen Bai, Yuntao Guan

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1344-8

摘要： Abstract • A novel Bi2WO6/CuS composite was fabricated by a facile solvothermal method. • This composite efficiently removed organic pollutants and Cr(VI) by photocatalysis. • The DOM could promoted synchronous removal of organic pollutants and Cr(VI). • This composite could be applied at a wide pH range in photocatalytic reactions. • Possible photocatalytic mechanisms of organic pollutants and Cr(VI) were proposed. A visible-light-driven Bi2WO6/CuS p-n heterojunction was fabricated using an easy solvothermal method. The Bi2WO6/CuS exhibited high photocatalytic activity in a mixed system containing rhodamine B (RhB), tetracycline hydrochloride (TCH), and Cr (VI) under natural conditions. Approximately 98.8% of the RhB (10 mg/L), 87.6% of the TCH (10 mg/L) and 95.1% of the Cr(VI) (15 mg/L) were simultaneously removed from a mixed solution within 105 min. The removal efficiencies of TCH and Cr(VI) increased by 12.9% and 20.4%, respectively, in the mixed solution, compared with the single solutions. This is mainly ascribed to the simultaneous consumption electrons and holes, which increases the amount of excited electrons/holes and enhances the separation efficiency of photogenerated electrons and holes. Bi2WO6/CuS can be applied over a wide pH range (2–6) with strong photocatalytic activity for RhB, TCH and Cr(VI). Coexisiting dissolved organic matter in the solution significantly promoted the removal of TCH (from 74.7% to 87.2%) and Cr(VI) (from 75.7% to 99.9%) because it accelerated the separation of electrons and holes by consuming holes as an electron acceptor. Removal mechanisms of RhB, TCH, and Cr(VI) were proposed, Bi2WO6/CuS was formed into a p-n heterojunction to efficiently separate and transfer photoelectrons and holes so as to drive photocatalytic reactions. Specifically, when reducing pollutants (e.g., TCH) and oxidizing pollutants (e.g., Cr(VI)) coexist in wastewater, the p-n heterojunction in Bi2WO6/CuS acts as a “bridge” to shorten the electron transport and thus simultaneously increase the removal efficiencies of both types of pollutants.

关键词： Photocatalysis     Bi2WO6/CuS     Organic pollutants     Cr(VI)     Synergistic effect    

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标题 作者 时间 类型 操作

Multimedia distribution and health risk assessment of typical organic pollutants in a retired industrial

期刊论文

Immobilization of laccase on organic–inorganic nanocomposites and its application in the removal of phenolicpollutants

期刊论文

Addressing the environmental risk of persistent organic pollutants in China

Bin WANG, Jun HUANG, Shubo DENG, Xiaoling YANG, Gang YU

期刊论文

DEGRADATION OF ORGANIC POLLUTANTS IN FLOCCULATED LIQUID DIGESTATE USING PHOTOCATALYTIC TITANATE NANOFIBERS

期刊论文

Corrigendum to “Emerging Organic Contaminants in Chinese Surface Water: Identification of Priority Pollutants

Mengmeng Zhong, Tielong Wang, Wenxing Zhao, Jun Huang, Bin Wang, Lee Blaney, Qingwei Bu, Gang Yu

期刊论文

Endosulfan in the Chinese environment: monitoring and modeling

Hongliang JIA, Liyan LIU, Yeqing SUN, Daoji CAI, Jianxin HU, Nanqi REN, Yifan LI

期刊论文

Perfluoroalkane acids in human milk under the global monitoring plan of the Stockholm Convention on Persistent OrganicPollutants (2008–2019)

期刊论文

Predictive models on photolysis and photoinduced toxicity of persistent organic chemicals

Qing ZHANG

期刊论文

Kinetics of enhanced adsorption by polarization for organic pollutants on activated carbon fiber

HAN Yanhe, QUAN Xie, ZHAO Huimin, CHEN Shuo, ZHAO Yazhi

期刊论文

Effects of a diesel oxidation catalyst on gaseous pollutants and fine particles from an engine operating

Xiaoyan SHI, Kebin HE, Weiwei SONG, Xingtong WANG, Jihua TAN

期刊论文

Determination of persistent organic pollutants by gas chromatography/laser multiphoton ionization/time-of-flight

Osamu SHITAMICHI, Taiki MATSUI, Yamei HUI, Weiwei CHEN, Totaro IMASAKA

期刊论文

Twenty years of achievements in China’s implementation of the Stockholm Convention

期刊论文

The abatement of major pollutants in air and water by environmental catalysis

Junhua LI, Hong HE, Chun HU, Jincai ZHAO

期刊论文

Efficient elimination of environmental pollutants through sorption-reduction and photocatalytic degradation

Njud S. Alharbi, Baowei Hu, Tasawar Hayat, Samar Omar Rabah, Ahmed Alsaedi, Li Zhuang, Xiangke Wang

期刊论文

Fabrication of highly efficient Bi

Wei Mao, Lixun Zhang, Tianye Wang, Yichen Bai, Yuntao Guan

期刊论文